Sustainable Electrochemical Energy and ConversionHermawan Research Group, BRIN

Materials and methods for sustainable electrochemistry

Electrochemistry can store renewable electricity, turn water, CO2, nitrogen compounds, and biomass into fuels and chemicals, and detect what matters for health and the environment. Our work covers the materials that make these reactions efficient, the sustainable sources they can be made from, and the tools to watch them at work.

Electrocatalysis for fuels and chemicals

Renewable electricity can drive reactions that turn water, CO2, and nitrogen compounds into fuels and chemicals. We design catalysts for both electrodes. At the cathode we study hydrogen evolution, CO2 reduction, and the reduction of nitrogen, nitrate, and nitrogen oxides to ammonia. At the anode we study oxygen evolution and the oxidation of glycerol, glucose, and HMF, which may replace oxygen evolution with a reaction that yields a product of value.

  • Cathode reactions for hydrogen, carbon products, and ammonia
  • Anode reactions that pair biomass oxidation with hydrogen production
  • Linking catalyst structure to selectivity

Key papers

Fundamentals, rational catalyst design, and remaining challenges in electrochemical NOx reduction reaction. iScience, 2023

Upcycling air pollutants to fuels and chemicals via electrochemical reduction technology. Journal of Environmental Management, 2023

Autonomous high-throughput computations in catalysis. Chem Catalysis, 2022

An electrochemical cell with reduction reactions at the cathode and oxidation reactions at the anode

Energy storage

Defects decide how much charge an electrode can store and how fast it can release it. We study supercapacitor electrodes built on defect-rich metal oxides, conducting polymers, and biomass-derived carbon, and we examine how the electrolyte and its pH change their behaviour.

  • Defect engineering in oxide electrodes for supercapacitors
  • Biomass-derived activated carbon and its porosity
  • Electrolyte and pH effects on charge storage

Key papers

Material design and characterization of conducting polymer-based supercapacitors. Polymer Reviews, 2024

High energy density asymmetric supercapacitors enabled by La-induced defective MnO2 and biomass-derived activated carbon. Materials Letters, 2023

A supercapacitor with ions between two electrodes, beside a repeating charge and discharge curve

Sustainable materials from waste

We treat waste as a feedstock. Spent lithium-ion batteries are usually recycled for their raw metals, and we take a shorter route. Cathode leachates and used graphite anodes are converted directly into nanostructured materials and carbon supports. The same thinking extends to biomass and industrial residues, which become activated carbons and catalyst precursors.

  • Spent battery cathodes and anodes as sources of multi-metal catalysts and carbon supports
  • Biomass and industrial waste as sources of carbon and catalysts
  • Life cycle assessment to test whether upcycling routes lower environmental impact

Key papers

High-entropy layered oxide electrocatalyst derived from spent battery cathodes for overall water splitting and 2,5 hydroxymethylfurfural (HMF) oxidation. Materials Horizons, 2026

Quaternary layered double hydroxides from spent battery as electrocatalysts for the oxygen evolution reaction. International Journal of Hydrogen Energy, 2024

A spent battery is split into metal leachate and used graphite, which become nanostructured materials and graphene supports for new catalysts

Chemical and electrochemical sensing

Sensing is where this research began. Earlier work on metal oxides and MXenes showed how surface structure controls the response to gases such as NO2, acetone, and toluene. The same thinking now guides electrochemical sensors for dopamine, pesticides, food antioxidants, and disease markers, where nanomaterial electrodes are tuned to detect targets at low concentrations.

  • Gas sensors based on metal oxides and MXenes
  • Non-enzymatic electrochemical sensors and immunosensors
  • Two-dimensional materials for breath-based and point-of-care diagnostics

Key papers

Nanomaterial-based electrochemical sensors for phenolic antioxidants in foods and beverages. Methods, 2026

Achieving high-performance NO2 sensors via vertically-aligned Ti3C2Tx nanoarchitectures. Sensors and Actuators B: Chemical, 2025

Tailoring NiFeOx nanostructures with molten salts synthesis for non-enzymatic electrochemical sensing of dopamine. Journal of Solid State Electrochemistry, 2025

Advanced strategies to improve performances of molybdenum-based gas sensors. Nano-Micro Letters, 2021

Target molecules bind to a nanostructured surface and produce a signal peak that grows with concentration

Operando and in situ spectroscopy

A catalyst or electrode rarely looks the same at work as it does on the bench. We follow materials while the reaction runs, combining synchrotron X-ray absorption and scattering with in situ Raman, infrared, and UV-Vis spectroscopy. Each probe answers a different question, from oxidation state and local structure to surface phases and adsorbed intermediates.

  • Operando X-ray absorption spectroscopy and X-ray scattering at synchrotron facilities
  • In situ Raman and infrared spectroscopy of surface phases and reaction intermediates
  • In situ UV-Vis spectroscopy of electronic and optical changes during reaction

Key papers

Add papers that use operando or in situ methods.

A working electrochemical cell probed by X-ray absorption, Raman, infrared, and UV-Vis spectroscopy

AI and machine learning in electrochemistry

Electrochemical experiments produce more data than a person can read by eye. We use machine learning and automated computation to find patterns in that data, to screen candidate catalysts before they are made, and to make synthesis from variable waste feedstocks more reproducible.

  • Machine learning models that link composition and structure to performance
  • Automated, high-throughput computation for catalyst screening
  • Data-driven control of synthesis from waste feedstocks, where every batch differs

Key papers

Autonomous high-throughput computations in catalysis. Chem Catalysis, 2022

Experimental data feed a machine learning model, which suggests the best next experiment, and each new result retrains the model

Grants and projects

Our work is supported by national funding and by competitive international programmes that give access to advanced facilities.

Research grants

ProjectFunderPeriod
RECO2VER. Utilizing industrial and biomass waste-derived catalysts for recycling CO2 into high-value energy resourcesLPDP RIIM through the Southeast Asia-Europe Joint Funding Scheme2025 to 2028
Two-dimensional materials as biomarker-based sensing materials towards point-of-care disease monitoringLPDP RIIM, BRIN2023 to 2026
Upcycling waste battery materials into electrocatalysts for tandem production of hydrogen and biomass conversionNEDO and the Embassy of France2023 to 2025
Waste batteries as electrocatalysts for green electrochemical processesSTIC Research and Publishing Grant2024
Tandem electrocatalysts for hydrogen production and biomass valorization, with CNRS-IRCELYONScience et Impact, Institut francais d'Indonesie and the Embassy of France2024

Facility access and beamtime

ProgrammeWhat it supportsHostPeriod
ReMade@ARILaser processing, in situ electrochemistry, and electron microscopyCLL, Coimbra and NIMP, Bucharest2026
RISEnergy Transnational AccessResearch stay on energy materialsKarlsruhe Institute of TechnologyTo be scheduled
EXCITEAtomic force and electron microscopyUniversity of GranadaTo be scheduled
EMERGESustainable printable electronics using recycled battery materialsRISE, Norrkoping2026
Synchrotron Light Research InstituteX-ray scattering and operando X-ray absorption spectroscopySLRI, Thailand2026
ISIS Neutron and Muon SourceNeutron scattering on the MAPS and TOSCA instrumentsISIS, United Kingdom2024